ELECTRON BACKSCATTER DIFFRACTION (EBSD): A NEW TECHNIQUE FOR THE IDENTIFICATION OF PIGMENTS AND RAW MATERIALS IN HISTORIC GLASSES AND CERAMICS.

Coloured samples of glass and ceramic were selected for EBSD investigation to verify the potential (advantages and limitations) of this technique in the characterization of the raw materials used and the neoformation phases originating from the manufacturing processes. In the case of copper-bearing...

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Publicado en:Archaeometry Vol. 53; no. 1; pp. 178 - 194
Autores principales: PERUZZO, L., FENZI, F., VIGATO, P. A.
Formato: Artículo
Publicado: Wiley-Blackwell Feb2011
Materias:
Acceso en línea:Ver este registro en EBSCOhost
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        10.1111/j.1475-4754.2010.00540.x
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        atl: ELECTRON BACKSCATTER DIFFRACTION (EBSD): A NEW TECHNIQUE FOR THE IDENTIFICATION OF PIGMENTS AND RAW MATERIALS IN HISTORIC GLASSES AND CERAMICS.
      aug:
        au:
          PERUZZO, L.
          FENZI, F.
          VIGATO, P. A.
        affil:
          CNR Istituto di Geoscienze e Georisorse, Via Matteotti, 30, 35137 Padova, Italy
          CNR Istituto di Chimica Inorganica e delle Superfici, C.so Stati Uniti, 4, 35127 Padova, Italy
      su:
        Electron backscattering
        Optical diffraction
        Ceramics
        Production methods
        Industrial chemistry
        Manufacturing processes
        Copper alloys
        Prehistoric glass
      sug:
        subj:
          Electron backscattering
          Optical diffraction
          Ceramics
          Production methods
          Industrial chemistry
          Manufacturing processes
          Copper alloys
          Prehistoric glass
      ab: Coloured samples of glass and ceramic were selected for EBSD investigation to verify the potential (advantages and limitations) of this technique in the characterization of the raw materials used and the neoformation phases originating from the manufacturing processes. In the case of copper-bearing red glasses, it was verified that micrometric droplets, residuals of the original copper source, can be ascribed to metallic copper or to a low-Sn bronze, due to strongly similar lattice parameters. From the same samples, micrometric flakes were identified by EBSD as magnetite and interpreted as residues of the reducing agent used in the production of such red glasses. Further, the technique allowed the pigment responsible for the yellow colouring of some incised slipware to be recognized as bindheimite. In a third case, the black pigment, contained in some Nestorian decorated pottery, was identified as an amorphous phase of Mn oxide. The accurate identification of the colouring particles and other products or materials offered a more precise comprehension of the production technique, period and site of the examined artefacts, together with scientific parameters for the identification of the raw materials, their transformation during the production cycle and an evaluation of the most reliable recipes used for their preparation.
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    language: English
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