Advanced Electron Paramagnetic Resonance and Density Functional Theory Study of a (2Fe3S) Cluster Mimicking the Active Site of [FeFe] Hydrogenase.

Despite extensive investigations of the active site of the [FeFe] hydrogenases, many details concerning the properties of the "hydrogen converting cluster" are not yet fully understood. The complexity of the so-called H-cluster is one of the main difficulties in studying the properties of its compon...

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Publicado en:	Journal of the American Chemical Society Vol. 132; no. 49; pp. 17578 - 17588
Autores principales:	Silakov, Alexey, Shaw, Jennifer L., Reijerse, Eduard J., Lubitz, Wolfgang
Formato:	Artículo
Publicado:	American Chemical Society 12/15/2010
Materias:	Hydrogenase Electron paramagnetic resonance Density functionals Oxidation-reduction reaction Nuclear isomers Particles (Nuclear physics)
Acceso en línea:	Ver este registro en EBSCOhost