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Bridging the Gap between Electrochemical and Organometallic Activation: Benzyl Chloride Reduction at Silver Cathodes.

Integration of voltammetry, surface-enhanced Raman spectroscopy (SERS), and density functional theory (DFT) has allowed unraveling the mechanistic origin of the exceptional electrocatalytic properties of silver cathodes during the reduction of benzyl chloride. At inert electrodes the initial reducti...

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Publicado en:Journal of the American Chemical Society Vol. 132; no. 48; pp. 17199 - 17211
Autores principales: Yi-Fan Huang, De-Yin Wu, An Wang, Bin Ren, Rondinini, Sandra, Zhong-Qun Tian, Amatore, Christian
Formato: Artículo
Publicado: American Chemical Society 12/8/2010
Materias:
Organometallic chemistry
Transition metal complexes
Voltammetry
Raman spectroscopy
Density functionals
Silver
Cathodes
Acceso en línea:Ver este registro en EBSCOhost