Density Functional Theory Study of the Mechanisms and Stereochemistry of the Rh(I)-Catalyzed Intramolecular [3+2] Cycloadditions of 1-Ene- and 1-Yne-Vinylcyclopropanes.

The mechanisms, structures of all stationary points involved, and kinetic and thermodynamic parameters of the Rh(l)-catalyzed intramolecular [3+2] cycloaddition reactions of 1-eneand 1-yne-vinylcyclopropanes (1-ene-VCPs and 1-yne-VCP5) have been investigated using density functional theory (DFT) cal...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 133; no. 3; pp. 447 - 462
Main Authors:	Lei Jiao, Mu Lin, Zhi-Xiang Yu
Format:	Article
Published:	American Chemical Society 1/26/2011
Subjects:	Ring formation (Chemistry) Stereochemistry Density functionals Organic synthesis Alkenes Cyclopropane Hydrides
Online Access:	View this record in EBSCOhost