SIC Silagraphene and Its One-Dimensional Derivatives: Where Planar Tetracoordinate Silicon Happens.

The periodic systems containing planar tetracoordinate silicon (ptSi), SiC silagraphene, nanotubes, and nanoribbons, were predicted by means of density functional theory (DFT) computations. In SiC silagraphene, each silicon atom is bonded by four carbon atoms in a pure plane, representing the first...

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Published in:Journal of the American Chemical Society Vol. 133; no. 4; pp. 900 - 909
Main Authors: Yafei Li, Fengyu Li, Zhen Zhou, Zhongfang Chen
Format: Article
Published: American Chemical Society 2/2/2011
Subjects:
Online Access:View this record in EBSCOhost
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        10.1021/ja107711m
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        atl: SIC Silagraphene and Its One-Dimensional Derivatives: Where Planar Tetracoordinate Silicon Happens.
      aug:
        au:
          Yafei Li
          Fengyu Li
          Zhen Zhou
          Zhongfang Chen
        affil:
          Institute of New Energy Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Tianjin Key Laboratory of Metal and Molecule Based Material Chemistry, Nankai University, Tianjin 300071, China
          Department of Chemistry, Institute for Functional Nanomaterials, University of Puerto Rico, Rio Piedras Campus, San Juan 00931, Puerto Rico
      su:
        Silicon carbide
        Graphene
        Nanotubes
        Density functionals
        Silicon
        Carbon
        Chirality
      sug:
        subj:
          Silicon carbide
          Graphene
          Nanotubes
          Density functionals
          Silicon
          Carbon
          Chirality
      ab: The periodic systems containing planar tetracoordinate silicon (ptSi), SiC silagraphene, nanotubes, and nanoribbons, were predicted by means of density functional theory (DFT) computations. In SiC silagraphene, each silicon atom is bonded by four carbon atoms in a pure plane, representing the first anti-vant Hoff/Lebel species in the Si-containing extended system. SiC nanotubes, rolled up by the SiC silagraphene, exhibit excellent elastic properties. All these ptSicontaining nanomaterials are metallic, regardless of the chirality, tube diameter, or ribbon width. The high stabilities of these systems strongly suggest the feasibility for their experimental realizations.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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