PhP(BH)Li: From Ditopicity to Dual Reactivity.

A multinuclear NMR study shows that the deprotonation of diphenyiphosphine-orane by n-BuLi in THF leads to a disolvated lithium phosphido-borane Ph2P(BH3)Li of which L1 is connected to the hydrides on the boron and two THF molecules rather than to the phosphorus. This entity behaves as both a phosph...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 133; no. 16; pp. 6472 - 6481
Main Authors:	Consiglio, Gabriella Barozzino, Queval, Pierre, Harrison-Marchand, Anne, Mordini, Alessandro, Lohier, Jean-Francois, Delacroix, Olivier, Gaumont, Annie-Claude, Gérard, Hélëne, Maddaluno, Jacques, Oulyadit, Hassan
Format:	Article
Published:	American Chemical Society 4/27/2011
Subjects:	Nuclear magnetic resonance Proton transfer reactions Boranes Density functionals Phosphorus
Online Access:	View this record in EBSCOhost