Selective Dilithiation of [Ti(q-CH)(η-CH)] and Subsequent Conversion into Neutral and Cationic ansa-Complexes.
Selective dimetalation of a sandwich complex featuring the cyclooctatetraene ligand has been accomplished for the first time. The isolation of the dilithiated species 1 subsequently enabled the isolation of a paramagnetic [2]stannatitanoarenophane (2) via salt elimination reaction. Chemical oxidatio...
| Publicado en: | Journal of the American Chemical Society Vol. 133; no. 15; pp. 5780 - 5784 |
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| Autores principales: | , , , |
| Formato: | Artículo |
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American Chemical Society
4/20/2011
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| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=60793821&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 60793821 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 4/20/2011 vid: 133 iid: 15 pid: 997 pub: American Chemical Society artinfo: ui: 60793821 10.1021/ja2014218 ppf: 5780 ppct: 4 formats: tig: atl: Selective Dilithiation of [Ti(q-CH)(η-CH)] and Subsequent Conversion into Neutral and Cationic ansa-Complexes. aug: au: Braunschweig, Holger Fuss, Marco Kupfer, Thomas Radacki, Krzysztof affil: Institut für Anorganische Chemie, Julius-Maximilians Universität Würzburg, Am Hubland, 97074 Würzburg, Germany su: Complex compounds Ligands (Chemistry) Oxidation Proton transfer reactions Chemical reactions X-ray diffraction sug: subj: Complex compounds Ligands (Chemistry) Oxidation Proton transfer reactions Chemical reactions X-ray diffraction ab: Selective dimetalation of a sandwich complex featuring the cyclooctatetraene ligand has been accomplished for the first time. The isolation of the dilithiated species 1 subsequently enabled the isolation of a paramagnetic [2]stannatitanoarenophane (2) via salt elimination reaction. Chemical oxidation resulted in the formation of a rare example of a cationic ansa-complex (3). pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2011 holdings: @attributes: islocal: N |
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