Transmetalation of Methyl Groups Supported by Pt--Au Bonds in the Gas Phase, in Silico, and in Solution.

We report Pt-to-Au methyl transfer reactions that occur in the gas phase and in solution. The heterobimetallic Pt/Au complexes {[(dmpe)PtMe][AuPR]} (R = Me (2a), Ph (2b), Bu (2c)), observed in the gas phase by means of electrospray ionization, were subjected to collision induced dissociation (CID) f...

Descripción completa

Detalles Bibliográficos

Publicado en:	Journal of the American Chemical Society Vol. 133; no. 23; pp. 8914 - 8927
Autores principales:	Serra, Daniel, Moret, Marc-Etienne, Chen, Peter
Formato:	Artículo
Publicado:	American Chemical Society 6/15/2011
Materias:	Methyl groups Scission (Chemistry) Electrospray ionization mass spectrometry Density functionals Dissociation (Chemistry) Chemistry
Acceso en línea:	Ver este registro en EBSCOhost