Adiabatic Versus Nonadiabatic Photoisomerization in Photochromic Ruthenium Sulfoxide Complexes: A Mechanistic Picture from Density Functional Theory Calculations.
Polypyridine ruthenium sulfoxide complexes are intriguing compounds which can display both photochromic and electrochromic properties. These properties are based on the Ru-S → Ru-O linkage isomerization capability of the sulfoxide group. The photoisomerization mechanism is of particular importance i...
| Publicado en: | Journal of the American Chemical Society Vol. 133; no. 24; pp. 9172 - 9175 |
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| Autores principales: | , , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
6/22/2011
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |