Density Functional Theory Study of the Mechanism and Origins of Stereoselectivity in the Asymmetric Simmons -- Smith Cyclopropanation with Charette Chiral Dioxaborolane Ligand.
Asymmetric Simmons-Smith reaction using Charette chiral dioxaborolane ligand is a widely applied method for the construction of enantiomerically enriched cyclopropanes. The detailed mechanism and the origins of stereoselectivity of this important reaction were investigated using density functional t...
| Publicado en: | Journal of the American Chemical Society Vol. 133; no. 24; pp. 9343 - 9354 |
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| Autores principales: | , , |
| Formato: | Artículo |
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American Chemical Society
6/22/2011
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |