Isomerization Mechanism in Hydrazone-Based Rotary Switches: Lateral Shift, Rotation, or Tautomerization?

Two intramolecularly hydrogen-bonded aryihy- drazone (aryl = phenyl or naphthyl) molecular switches have been synthesized, and their full and reversible switching between the E and Z configurations have been demonstrated. These chemically controlled configurational rotary switches exist primarily as...

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Publicado en:	Journal of the American Chemical Society Vol. 133; no. 25; pp. 9812 - 9824
Autores principales:	Landge, Shainaz M., Tkatchouk, Ekatarina, Benítez, Diego, Lanfranchi, Don Antoine, Elhabiri, Mourad, Goddard III, William A., Aprahamian, Ivan
Formato:	Artículo
Publicado:	American Chemical Society 6/29/2011
Materias:	Hydrogen bonding Isomerization Hydrazones Density functionals Proton transfer reactions Chemical bonds
Acceso en línea:	Ver este registro en EBSCOhost