Spin Crossover in a Four-Coordinate Iron(II) Complex.

The four-coordinate iron(II) phosphoraniminato complex PhB(MesIm)Fe-N-PPh undergoes an S = 0 to S = 2 spin transition with T = 81 K, as determined by variable-temperature magnetic measurements and Mössbauer spectroscopy. Variable-temperature single-crystal X-ray diffraction revealed that the S = 0 t...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 133; no. 11; pp. 2824 - 2828
Main Authors:	Scepaniak, Jeremiah J., Harris, T. David, Vogel, Carola S., Sutter, Jörg, Meyer, Karsten, Smith, Jeremy M.
Format:	Article
Published:	American Chemical Society 3/23/2011
Subjects:	Iron Magnetic measurements Spectrum analysis Temperature X-rays Optical diffraction Electronic structure
Online Access:	View this record in EBSCOhost