Intermediate-Assisted Multifunctional Catalysis in the Conversion of Flavin to 5,6-Dimethylbezimidazole by BluB: A Density Functional Theory Study.
BluB is a distinct flavin destructase that catalyzes a complex oxygen-dependent conversion of reduced flavin mononucleotide (FMNH) to form 5,6-dimethylbenzimidazole (DMB), the lower ligand of vitamin B. The catalyzed mechanism remains a challenge due to the discrepancy between the complexity of the...
| Publicado en: | Journal of the American Chemical Society Vol. 133; no. 11; pp. 4079 - 4092 |
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| Autores principales: | , |
| Formato: | Artículo |
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American Chemical Society
3/23/2011
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| Acceso en línea: | Ver este registro en EBSCOhost |