Stepwise Synthesis of Metal - Organic Frameworks: Replacement of Structural Organic Linkers.
We demonstrate how a single-crystal to single-crystal transformation resulting from bridging-linker replacement is possible in extended 2D and 3D metal-organic frameworks (MOFs) by introducing pillared paddlewheel MOF structures into a solution containing dipyridyl linkers. No lateral movement of th...
| Publicado en: | Journal of the American Chemical Society Vol. 133; no. 26; pp. 9984 - 9988 |
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| Autores principales: | , , , |
| Formato: | Artículo |
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American Chemical Society
7/6/2011
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| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=63149602&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 63149602 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 7/6/2011 vid: 133 iid: 26 pid: 997 pub: American Chemical Society artinfo: ui: 63149602 10.1021/ja201911v ppf: 9984 ppct: 4 formats: tig: atl: Stepwise Synthesis of Metal - Organic Frameworks: Replacement of Structural Organic Linkers. aug: au: Burnett, Brandon J. Barron, Paul M. Chunhua Hu Wonyoung Choe affil: Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska 68588-0304, United States Nebraska Center for Materials and Nanoscience, University of Nebraska-Lincoln, Lincoln, Nebraska 68588-0304, United States Department of Chemistry, New York University, New York, New York 10003-6688, United States su: Crystallography Structural frames Metals Crystal growth Crystallization sug: subj: Crystallography Structural frames Metals Crystal growth Crystallization ab: We demonstrate how a single-crystal to single-crystal transformation resulting from bridging-linker replacement is possible in extended 2D and 3D metal-organic frameworks (MOFs) by introducing pillared paddlewheel MOF structures into a solution containing dipyridyl linkers. No lateral movement of the layers was observed during this transformation, creating a templating effect from the "parent" structure to the "daughter" structure. A previously unattainable structure was obtained by a two-step synthetic method utilizing the bridging-linker replacement transformation method. Additionally, a bridging-linker insertion was observed when excess linker was used with the 2D MOF structure, inducing an overall 2D to 3D transformation. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2011 holdings: @attributes: islocal: N |
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