Mechanisms of the Thermal Cyclotrimerizations of Fluoro- and Chloroacetylenes: Density Functional Theory Investigation and Intermediate Trapping Experiments.

Theoretical studies of the mechanisms of the thermal cyclotrimerization of fluoro- and chloroacetylenes, which were reported by Viehe and Ballester, respectively, were conducted with the aid of density functional theory calculations of the (U)B3LYP functional, indicating that the thermal cyclotrimer...

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Publicado en:Journal of the American Chemical Society Vol. 133; no. 28; pp. 10864 - 10878
Autores principales: Zhong-Ke Yao, Zhi-Xiang Yu
Formato: Artículo
Publicado: American Chemical Society 7/20/2011
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Acceso en línea:Ver este registro en EBSCOhost