Interaction of a Weakly Acidic Dinitroaromatic with Alkylamines: Avoiding the Meisenheimer Trap.

Polynitroaromatics are well-known to form anionic s-complexes (Meisenheimer complexes). The formation of such complexes was assumed in the past to explain the blue color of solutions of 2,4-dinitrotoluene (DNT) and amines. However, this work shows that caution is warranted to avoid the hasty misiden...

Descripción completa

Detalles Bibliográficos

Publicado en:	Journal of the American Chemical Society Vol. 133; no. 32; pp. 12858 - 12866
Autores principales:	Olson, Eric J., Teng T. Xiong, Cramer, Christopher J., Böhlmann, Philippe
Formato:	Artículo
Publicado:	American Chemical Society 8/17/2011
Materias:	Addition polymerization Complex compounds Dinitrotoluenes Density functionals Aromaticity
Acceso en línea:	Ver este registro en EBSCOhost