Ultrafast and Continuous Synthesis of Unaccommodating Inorganic Nanomaterials in Droplet- and Ionic Liquid-Assisted Microfluidic System.

Despite many efforts on the synthesis of inorganic nanomaterials with uniform structure and narrow size distribution in a fast and continuous way, it is still a critical challenge in the chemistry research community due to the uncontrollable mass and heat transfer and the harsh experimental conditio...

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Publicado en:Journal of the American Chemical Society Vol. 133; no. 37; pp. 14765 - 14771
Autores principales: Phan Huy Hoang, HoSeok Park, Dong-Pyo Kim
Formato: Artículo
Publicado: American Chemical Society 9/21/2011
Materias:
Acceso en línea:Ver este registro en EBSCOhost
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      dt: 9/21/2011
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      pub: American Chemical Society
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        10.1021/ja2054429
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        atl: Ultrafast and Continuous Synthesis of Unaccommodating Inorganic Nanomaterials in Droplet- and Ionic Liquid-Assisted Microfluidic System.
      aug:
        au:
          Phan Huy Hoang
          HoSeok Park
          Dong-Pyo Kim
        affil:
          National Creative Research Center of Applied Microfluidic Chemistry, Chungnam National University, Daejeon 305-764, South Korea
          Department of Chemical Engineering, College of Engineering, KyungHee University, 1 Seochon-dong, Giheung-gu, Youngin-si, Gyeonggi-do 446-701, Korea
          Graduate School of Analytical Science and Technology, Chungnam National University, Daejeon 305-764, South Korea
      su:
        Nanostructured materials
        Ionic liquids
        Microfluidics
        Uniform spaces
        Microreactors
        Microfluidic analytical techniques
      sug:
        subj:
          Nanostructured materials
          Ionic liquids
          Microfluidics
          Uniform spaces
          Microreactors
          Microfluidic analytical techniques
      ab: Despite many efforts on the synthesis of inorganic nanomaterials with uniform structure and narrow size distribution in a fast and continuous way, it is still a critical challenge in the chemistry research community due to the uncontrollable mass and heat transfer and the harsh experimental conditions of high temperature and pressure. Here we report a droplet- and ionic liquid-assisted microfluidic (DIM) synthesis method, which takes full advantage of both ionic liquids and droplet-assisted microreaction systems, for an ultrafast, mild, and continuous synthesis of various inorganic nanomaterials that takes only tens of minutes rather than days that are usually needed to synthesize. In particular, unaccommodating inorganic nanomaterials that are difficult to produce, such as nanoporous ZSM-5, γ-AlOOH, and β-FeOOH nanorods, were synthesized in only "20 minutes" of reaction time even with simple instrument. The DIM method delineated herein would offer a breakthrough synthetic approach for functional but unaccommodating inorganic nanomaterials in a continuous and mild manner.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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