Nickel-Thiolate Complex Catalyst Assembled in One Step in Water for Solar HProduction.
We report the use of a simple complex assembled from Ni(II) salt and 2-mecaptoethanol in one step in water as the efficient catalyst in a molecular hydrogen system which can be sensitized by a low-cost xanthene dye, Erythrosin B. An excellent quantum efficiency of 24.5% is attained at 460 nm. This s...
| Publicado en: | Journal of the American Chemical Society Vol. 133; no. 51; pp. 20680 - 20684 |
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| Autores principales: | , , , , , |
| Formato: | Artículo |
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American Chemical Society
12/28/2011
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=70199383&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 70199383 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 12/28/2011 vid: 133 iid: 51 pid: 997 pub: American Chemical Society artinfo: ui: 70199383 10.1021/ja208555h ppf: 20680 ppct: 4 formats: tig: atl: Nickel-Thiolate Complex Catalyst Assembled in One Step in Water for Solar HProduction. aug: au: Wei Zhang Jindui Hong Jianwei Zheng Zhiyan Huang Zhou, Jianrong (Steve) Rong Xu affil: School of Chemical & Biomedical Engineering, Nanyang Technological University, 62, Nanyang Drive, Singapore 637459, Singapore Institute of High Performance Computing, Agency for Science, Technology and Research, 1 Fusionopolis Way, #16-16 Connexis, 138632, Singapore School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore su: Catalysts Xanthene dyes Hydrogen Nickel Photocatalysis Transition metals Transition metal thiolates Nickel thiolate sug: subj: Catalysts Xanthene dyes Hydrogen Nickel Photocatalysis Transition metals Transition metal thiolates Nickel thiolate ab: We report the use of a simple complex assembled from Ni(II) salt and 2-mecaptoethanol in one step in water as the efficient catalyst in a molecular hydrogen system which can be sensitized by a low-cost xanthene dye, Erythrosin B. An excellent quantum efficiency of 24.5% is attained at 460 nm. This simple system is expected to contribute toward the development of economical and environmentally benign solar hydrogen production systems. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2011 holdings: @attributes: islocal: N |
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