Reaction Mechanism in Crystalline Solids: Kinetics and Conformational Dynamics of the Norrish Type II Biradicals from α- Adamantyl-p-Methoxyacetophenone.

In an effort to determine the details of the solid-state reaction mechanism and diastereoselectivity in the Norrish type II and Yang cyclization of crystalline α-adamantyl-p-methoxyacetophenone, we determined its solid-state quantum yields and transient kinetics using nanocrystalline suspensions. Th...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 2; pp. 1115 - 1124
Autores principales:	Kuzmanich, Gregory, Vogelsberg, Cortnie S., Maverick, Emily F., Netto-Ferreira, José Carlos, Scaiano, J. C., Garcia-Garibay, Miguel A.
Formato:	Artículo
Publicado:	American Chemical Society 1/18/2012
Materias:	Crystallography Nuclear magnetic resonance spectroscopy Hydrogen Optical diffraction Relaxation (Nuclear physics) Spin-lattice relaxation
Acceso en línea:	Ver este registro en EBSCOhost