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Carbon-Oxygen Bond Formation via Organometallic Baeyer-Villiger Transformations: A Computational Study on the Impact of Metal Identity.

Metal-mediated formation of C-O bonds is an important transformation that can occur by a variety of mechanisms. Recent studies suggest that oxygen-atom insertion into metal-hydrocarbyl bonds in a reaction that resembles the Baeyer-Villiger transformation is a viable process. In an effort to identify...

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Published in:Journal of the American Chemical Society Vol. 134; no. 4; pp. 2332 - 2340
Main Authors: Figg, Travis M., Webb, Joanna R., Cundari, Thomas R., Gunnoe, T. Brent
Format: Article
Published: American Chemical Society 2/1/2012
Subjects:
Chemical bonds
Organometallic chemistry
Chemical reactions
Density functionals
Chemical structure
Oxidation
Online Access:View this record in EBSCOhost