Closely Stacked Oligo(phenylene ethynylene)s: Effect of π-Stacking on the Electronic Properties of Conjugated Chromophores.

In this work, a bicyclo[4.4.1]undecane scaffold is used to hold oligo(phenylene ethynylene) units in a cofacially stacked arrangement along the entire length of the conjugated units. We study the impact that the resulting strong interchain interactions have on the photophysical properties. The lengt...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 16; pp. 7176 - 7186
Autores principales:	Jagtap, Subodh P., Mukhopadhyay, Sukrit, Coropceanu, Veaceslav, Brizius, Glen L., Brédas, Jean-Luc, Collard, David M.
Formato:	Artículo
Publicado:	American Chemical Society 4/25/2012
Materias:	Stacking interactions Bioconjugates Oligomers Density functionals Chromophores Electric properties
Acceso en línea:	Ver este registro en EBSCOhost