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Electronic Spin Transition in Nanosize Stoichiometric Lithium Cobalt Oxide.

A change in the electronic spin state of the surfaces relevant to Li (de)intercalation of nanosized stoichiometric lithium cobalt oxide LiCo(III)O from low-spin to intermediate and high spin is observed for the first time. These surfaces are the ones that are relevant for Li (de)intercalation. From...

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Publicado en:Journal of the American Chemical Society Vol. 134; no. 14; pp. 6096 - 6100
Autores principales: Qian, Danna, Hinuma, Yoyo, Hailong Chen, Lin-Shu Du, Carroll, Kyler J., Ceder, Gerbrand, Grey, Clare P., Meng, Ying S.
Formato: Artículo
Publicado: American Chemical Society 4/11/2012
Materias:
Lithium cobalt oxide
Electron spin
Stoichiometry
Density functionals
Nanoparticles
Oxidation-reduction reaction
Lithium cell electrodes
Acceso en línea:Ver este registro en EBSCOhost