Mutual Exclusivity in the Synthesis of High Crystallinity and High Yield Single-Walled Carbon Nanotubes.

We report the mutually exclusive relationship between carbon nanotube (CNT) yield and crystallinity. Growth conditions were optimized for CNT growth yield and crystallinity through sequential tuning of three input variables: growth enhancer level, growth temperature, and carbon feedstock level. This...

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Publicado en:Journal of the American Chemical Society Vol. 134; no. 22; pp. 9219 - 9225
Autores principales: Kimura, Hiroe, Futaba, Don N., Yumura, Motoo, Hata, Kenji
Formato: Artículo
Publicado: American Chemical Society 6/6/2012
Materias:
Acceso en línea:Ver este registro en EBSCOhost
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      dt: 6/6/2012
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      pub: American Chemical Society
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        10.1021/ja300769j
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        atl: Mutual Exclusivity in the Synthesis of High Crystallinity and High Yield Single-Walled Carbon Nanotubes.
      aug:
        au:
          Kimura, Hiroe
          Futaba, Don N.
          Yumura, Motoo
          Hata, Kenji
        affil:
          Technology Research Association for Single Wall Carbon Nanotubes (TASC), Tsukuba 305-8565, Japan
          Japan Science and Technology Agency (JST), Kawaguchi 332-0012, Japan
          Department of Pure and Applied Sciences, Tsukuba University, Tsukuba 305-8573, Japan
          Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba 305-8565, Japan
      su:
        Single walled carbon nanotubes synthesis
        Crystallization
        Chemical vapor deposition
        Process optimization
        Feedstock
      sug:
        subj:
          Single walled carbon nanotubes synthesis
          Crystallization
          Chemical vapor deposition
          Process optimization
          Feedstock
      ab: We report the mutually exclusive relationship between carbon nanotube (CNT) yield and crystallinity. Growth conditions were optimized for CNT growth yield and crystallinity through sequential tuning of three input variables: growth enhancer level, growth temperature, and carbon feedstock level. This optimization revealed that, regardless of the variety of carbon feedstock and growth enhancer, the optimum conditions for yield and crystallinity differed significantly with yield/crystallinity, preferring lower/higher growth temperatures and higher/lower carbon feedstock levels. This mutual exclusivity stemmed from the inherent limiting mechanisms for each property.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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          year: 2012
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