[FeO(TBC)(CHCN)]: Comparative Reactivity of Iron(IV)-Oxo Species with Constrained Equatorial Cyclam Ligation.

[Fe=O(TBC)(CHCN)] (TBC = 1,4,8,1 1-tetrabenzyl-1,4,8,1 1-tetraazacyclotetradecane) is characterized, and its reactivity differences relative to O(TMC)(CHCN)] (TMC = 1,4,8,1 1-tetramethyl-1,4,8,1 1- tetraazacyclotetradecane) are evaluated in hydrogen atom (H- atom) abstraction and oxo-transfer reacti...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 28; pp. 11791 - 11807
Autores principales:	Wilson, Samuel A., Junying Chen, Seun-woo Hong, Yong-Min Lee, Clémancey, Martin, Garcia-Serres, Ricardo, Nomura, Takashi, Ogura, Takashi, Latour, Jean-Marc, Hedman, Britt, Hodgson, Keith O., Wonwoo Nam, Solomon, Edward I.
Formato:	Artículo
Publicado:	American Chemical Society 7/18/2012
Materias:	Reactivity (Chemistry) Comparative studies Iron compounds Oxo compounds Molecular structure Chemical research Density functionals X-ray spectroscopy
Acceso en línea:	Ver este registro en EBSCOhost