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Photoconversion Bonding Mechanism in Ruthenium Sulfur Dioxide Linkage Photoisomers Revealed by in Situ Diffraction.

Three new ruthenium-sulfur dioxide linkage photoisomeric complexes in the [Ru(NH)(SO)X]Cl∙HO family (X = pyridine (1); 3-chloropyridine (2); 4-chloropyridine (3)) have been developed in order to examine the effects of the trans-ligand on the nature of the photo-induced SO coordination to the rutheni...

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Publicado en:Journal of the American Chemical Society Vol. 134; no. 29; pp. 11860 - 11864
Autores principales: Sylvester, Sven O., Cole, Jacqueline M., Waddell, Paul G.
Formato: Artículo
Publicado: American Chemical Society 7/25/2012
Materias:
Isomers
Chemical bonds
Optical diffraction
Ruthenium compounds
Sulfur dioxide
Crystallography
Acceso en línea:Ver este registro en EBSCOhost