Causation in a Cascade: The Origins of Selectivities in Intramolecular Nitrone Cycloadditions.

The factors controlling chemo-, regio-, and stereoselectivity in a cascade of reactions starting from a bis(cyanoalkenyl)oxime and proceeding via nitrone cyclo- additions have been unraveled through a series of density functional theory calculations with several different functionals. Both kinetic a...

Descripción completa

Detalles Bibliográficos

Publicado en:	Journal of the American Chemical Society Vol. 134; no. 29; pp. 12010 - 12016
Autores principales:	Krenske, Elizabeth H., Agopcan, Sesil, Aviyente, Viktorya, Houk, K. N., Johnson, Brian A., Holmes, Andrew B.
Formato:	Artículo
Publicado:	American Chemical Society 7/25/2012
Materias:	Nitrones Ring formation (Chemistry) Regioselectivity (Chemistry) Density functionals Chemical models Thermodynamics
Acceso en línea:	Ver este registro en EBSCOhost