The Golden Pathway to Thiolate-Stabilized Nanoparticles: Following the Formation of Gold(I) Thiolate from Gold(III) Chloride.

Pathways for the formation of gold thiolate complexes from gold(III) chloride precursors AuCl and AuCl are examined. This work demonstrates that two distinct reaction pathways are possible; which pathway is accessible in a given reaction may depend on factors such as the residue group R on the incom...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 30; pp. 12590 - 12596
Autores principales:	Barngrover, Brian M., Aikens, Christine M.
Formato:	Artículo
Publicado:	American Chemical Society 8/1/2012
Materias:	Gold nanoparticle synthesis Thiolates Gold chloride Reaction mechanisms (Chemistry) Chemistry methodology Chemical synthesis Density functionals
Acceso en línea:	Ver este registro en EBSCOhost