Stable Alkanes Containing Very Long Carbon-Carbon Bonds.

The metal-induced coupling of tertiary diamondoid bromides gave highly sterically congested hydrocarbon (hetero)dimers with exceptionally long central C-C bonds of up to 1.71 Å in 2-(1-diamantyl)[121]tetramantane. Yet, these dimers are thermally very stable even at temperatures above 200 °C, which i...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 33; pp. 13641 - 13651
Autores principales:	Fokin, Andrey A., Chernish, Lesya V., Gunchenko, Pavel A., Tikhonchuk, Evgeniya Yu., Hausmann, Heike, MichaelvSerafin, Dahl, Jeremy E. P., Carlson, Robert M. K., Schreiner, Peter R.
Formato:	Artículo
Publicado:	American Chemical Society 8/22/2012
Materias:	Carbon-carbon bonds Alkane analysis Bromides Hydrocarbons Dimers Density functionals Nuclear magnetic resonance spectroscopy
Acceso en línea:	Ver este registro en EBSCOhost