Detection of the Water-Binding Sites of the Oxygen-Evolving Complex of Photosystem II Using W-Band 170 Electron-Electron Double Resonance-Detected NMR Spectroscopy.

Water binding to the MnOCa cluster of the oxygen-evolving complex (OEC) of Photosystem II (PSII) poised in the S state was studied via HO- and HO-labeling and high-field electron paramagnetic resonance (EPR) spectroscopy. Hyperfine couplings of coordinating O (I = /) nuclei were detected using W-ban...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 40; pp. 16619 - 16635
Autores principales:	Rapatskiy, Leonid, Cox, Nicholas, Savitsky, Anton, Ames, William M., Sander, Julia, Nowaczyk, Marc. M., Rögner, Matthias, Boussac, Alain, Neese, Frank, Messinger, Johannes, Lubitz, Wolfgang
Formato:	Artículo
Publicado:	American Chemical Society 10/10/2012
Materias:	Photosystems Nuclear magnetic resonance spectroscopy Photosynthetic oxygen evolution Electron paramagnetic resonance spectroscopy Density functionals
Acceso en línea:	Ver este registro en EBSCOhost