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Exploiting the π-Acceptor Properties of Carbene-Stabilized Phosphorus Centered Trications [LP] : Applications in Pt(II) Catalysis.

Reaction of tris(dimethylaminocyclopropenium) substituted phosphine 1 with KPtCl afforded the bench stable complex 3 which upon treatment with Ag[CBHCl] turned out to be an excellent catalyst for the transformation of a variety of ortho-biaryl substituted alkynes into polycyclic homo- and heteroaren...

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Publicado en:Journal of the American Chemical Society Vol. 134; no. 40; pp. 16753 - 16759
Autores principales: Carreras, Javier, Patil, Mahendra, Thiel, Walter, Alcarazo, Manuel
Formato: Artículo
Publicado: American Chemical Society 10/10/2012
Materias:
Carbenes
Cations
Phosphorus
Density functionals
Phosphorus compounds
Surface chemistry
Acceso en línea:Ver este registro en EBSCOhost