A Tetradentate Ligand for the Enantioselective Ti(IV)-Promoted Oxidation of Sulfides to Sulfoxides: Origin of Enantioselectivity.
A detailed stereomechanistic analysis has led to the design of a new tetradentate ligand for the enantioselective Ti(IV)-catalyzed oxidation of unsymmetrical sulfides to sulfoxides with high selectivity. The pathway of this oxidation and the closely related and long-known Kagan—Modena oxidation have...
| Publicado en: | Journal of the American Chemical Society Vol. 134; no. 42; pp. 17354 - 17358 |
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| Autores principales: | , , , , |
| Formato: | Artículo |
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American Chemical Society
10/24/2012
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=83146985&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 83146985 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 10/24/2012 vid: 134 iid: 42 pid: 997 pub: American Chemical Society artinfo: ui: 83146985 10.1021/ja305991k ppf: 17354 ppct: 4 formats: tig: atl: A Tetradentate Ligand for the Enantioselective Ti(IV)-Promoted Oxidation of Sulfides to Sulfoxides: Origin of Enantioselectivity. aug: au: Newhouse, Timothy R. Xin Li Blewett, Megan M. Whitehead, Clare M. C. Corey, E. J. affil: Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States su: Ligands (Chemistry) Enantioselective catalysis Oxidation Sulfides Sulfoxides Hydroperoxides Equilibrium constant (Chemistry) sug: subj: Ligands (Chemistry) Enantioselective catalysis Oxidation Sulfides Sulfoxides Hydroperoxides Equilibrium constant (Chemistry) ab: A detailed stereomechanistic analysis has led to the design of a new tetradentate ligand for the enantioselective Ti(IV)-catalyzed oxidation of unsymmetrical sulfides to sulfoxides with high selectivity. The pathway of this oxidation and the closely related and long-known Kagan—Modena oxidation have been clarified to identify the likely origin of the enantioselectivity. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2012 holdings: @attributes: islocal: N |
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