Elusive Metal-Free Primary Amination of Arylboronic Acids: Synthetic Studies and Mechanism by Density Functional Theory.

Herein, we disclose the first metal-free synthesis of primary aromatic amines from arylboronic acids, a reaction that has eluded synthetic chemists for decades. This remarkable transformation affords structurally diverse primary arylamines in good chemical yields, including a variety of halogenated...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 44; pp. 18253 - 18257
Autores principales:	Chen Zhu, Gongqiang Li, Ess, Daniel H., Falck, John R., Kürti, László
Formato:	Artículo
Publicado:	American Chemical Society 11/7/2012
Materias:	Amination Boronic acids Density functionals Aromatic amines Organic compounds
Acceso en línea:	Ver este registro en EBSCOhost