Combining Meyer–Schuster Rearrangement with Aldol and Mannich Reactions: Theoretical Study of the Intermediate Interception Strategy.

Interception of the transient allenyl enolate intermediate of the vanadium-catalyzed Meyer–Schuster rearrangement with aldehydes and imines has been studied computationally using density functional theory. Mechanistic details of the catalytic cycles for each of the reaction variants are established....

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 46; pp. 19159 - 19170
Autores principales:	Kalek, Marcin, Himo, Fahmi
Formato:	Artículo
Publicado:	American Chemical Society 11/21/2012
Materias:	Rearrangements (Chemistry) Computational chemistry Density functionals Mannich reaction Catalytic isomerization Intermediates (Chemistry) Carbon-carbon bonds synthesis Aldols
Acceso en línea:	Ver este registro en EBSCOhost