The Role of Order-Disorder Transitions in the Quest for Molecular Multiferroics: Structural and Magnetic Neutron Studies of a Mixed Valence Iron(II)-Iron(III) Formate Framework.

Neutron diffraction studies have been carried out to shed light on the unprecedented order-disorder phase transition (ca. 155 K) observed in the mixed-valence iron(II)-iron(III) formate framework compound [NH(CH)][FeFe(HCOO)]. The crystal structure at 220 K was first determined from Laue diffraction...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 48; pp. 19772 - 19782
Autores principales:	Cañadillas-Delgado, Laura, Fabelo, Oscar, Rodríguez-Velamazán, J. Alberto, Lemèe-Cailleau, Marie-Hélène, Mason, Sax A., Pardo, Emilio, Lloret, Francesc, Jiong-Peng Zhao, Xian-He Bu, Simonet, Virginie, Colin, Claire V., Rodríguez-Carvajal, Juan
Formato:	Artículo
Publicado:	American Chemical Society 12/5/2012
Materias:	Multiferroic materials Neutron diffraction Optical diffraction Iron Valence (Chemistry)
Acceso en línea:	Ver este registro en EBSCOhost