Dimensionality Transformation through Paddlewheel Reconfiguration in a Flexible and Porous Zn-Based Metal -- Organic Framework.

The reaction between Zn and a pyrene-based ligand decorated with benzoate fragments (HTBAPy) yields a 2D layered porous network with the metal coordination based on a paddlewheel motif. Upon desolvation the structure undergoes a significant and reversible structural adjustment with a corresponding r...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 50; pp. 20466 - 20479
Autores principales:	Stylianou, Kyriakos C., Rabone, Jeremy, Chong, Samantha Y., Heck, Romain, Armstrong, Jayne, Wiper, Paul V., Jelfs, Kim E., Zlatogorsky, Sergey, Bacsa, John, McLennan, Alec G., Ireland, Christopher P., Khimyak, Yaroslav Z., Thomas, K. Mark, Bradshaw, Darren, Rosseinsky, Matthew J.
Formato:	Artículo
Publicado:	American Chemical Society 12/19/2012
Materias:	Metal-organic frameworks Zinc Pyrene Coordinate covalent bond Xylene Ligand binding (Biochemistry) Porous materials synthesis
Acceso en línea:	Ver este registro en EBSCOhost