Dustiness of Fine and Nanoscale Powders.

Dustiness may be defined as the propensity of a powder to form airborne dust by a prescribed mechanical stimulus; dustiness testing is typically intended to replicate mechanisms of dust generation encountered in workplaces. A novel dustiness testing device, developed for pharmaceutical application,...

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Published in:Annals of Occupational Hygiene Vol. 57; no. 2; pp. 261 - 278
Main Authors: Evans, Douglas E., Turkevich, Leonid A., Roettgers, Cynthia T., Deye, Gregory J., Baron, Paul A.
Format: equations & formulas pictorial research tables/charts Journal Article
Published: Oxford University Press / USA Mar2013
Online Access:View this record in EBSCOhost
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      dt: Mar2013
      vid: 57
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      pub: Oxford University Press / USA
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        atl: Dustiness of Fine and Nanoscale Powders.
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        au:
          Evans, Douglas E.
          Turkevich, Leonid A.
          Roettgers, Cynthia T.
          Deye, Gregory J.
          Baron, Paul A.
        affil: National Institute for Occupational Safety and Health, Chemical Exposure and Monitoring Branch, Division of Applied Research and Technology , 4676 Columbia Parkway, MS-R7 , Cincinnati, OH 45226, USA
      sug:
        subj:
          Powders Analysis
          Dust Analysis
          Pharmaceutical Companies Adverse Effects
          Aerosols Adverse Effects
          Occupational Exposure Evaluation
          Environmental Monitoring Methods
          Environmental Monitoring Equipment and Supplies
          Nanoparticles
          Particle Size
          Videorecording
          Time Factors
          Human
          Photometry
          Parametric Statistics
          Descriptive Statistics
          Linear Regression
          Data Analysis Software
          Funding Source
      ab: Dustiness may be defined as the propensity of a powder to form airborne dust by a prescribed mechanical stimulus; dustiness testing is typically intended to replicate mechanisms of dust generation encountered in workplaces. A novel dustiness testing device, developed for pharmaceutical application, was evaluated in the dustiness investigation of 27 fine and nanoscale powders. The device efficiently dispersed small (mg) quantities of a wide variety of fine and nanoscale powders, into a small sampling chamber. Measurements consisted of gravimetrically determined total and respirable dustiness. The following materials were studied: single and multiwalled carbon nanotubes, carbon nanofibers, and carbon blacks; fumed oxides of titanium, aluminum, silicon, and cerium; metallic nanoparticles (nickel, cobalt, manganese, and silver) silicon carbide, Arizona road dust; nanoclays; and lithium titanate. Both the total and respirable dustiness spanned two orders of magnitude (0.3–37.9% and 0.1–31.8% of the predispersed test powders, respectively). For many powders, a significant respirable dustiness was observed. For most powders studied, the respirable dustiness accounted for approximately one-third of the total dustiness. It is believed that this relationship holds for many fine and nanoscale test powders (i.e. those primarily selected for this study), but may not hold for coarse powders. Neither total nor respirable dustiness was found to be correlated with BET surface area, therefore dustiness is not determined by primary particle size. For a subset of test powders, aerodynamic particle size distributions by number were measured (with an electrical low-pressure impactor and an aerodynamic particle sizer). Particle size modes ranged from approximately 300nm to several micrometers, but no modes below 100nm, were observed. It is therefore unlikely that these materials would exhibit a substantial sub-100nm particle contribution in a workplace.
      pubtype: Academic Journal
      doctype:
        equations & formulas
        pictorial
        research
        tables/charts
        Journal Article
      ougenre: Article
    language: English
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