Occupational Exposure Assessment in Carbon Nanotube and Nanofiber Primary and Secondary Manufacturers: Mobile Direct-Reading Sampling.

Research Significance: Toxicological evidence suggests the potential for a wide range of health effects from exposure to carbon nanotubes (CNTs) and carbon nanofibers (CNFs). To date, there has been much focus on the use of direct-reading instruments (DRIs) to assess multiple airborne exposure metri...

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Published in:Annals of Occupational Hygiene Vol. 57; no. 3; pp. 328 - 345
Main Authors: Dahm, Matthew M., Evans, Douglas E., Schubauer-Berigan, Mary K., Birch, M. Eileen, Deddens, James A.
Format: research tables/charts Journal Article
Published: Oxford University Press / USA Apr2013
Online Access:View this record in EBSCOhost
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      dt: Apr2013
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      pub: Oxford University Press / USA
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        atl: Occupational Exposure Assessment in Carbon Nanotube and Nanofiber Primary and Secondary Manufacturers: Mobile Direct-Reading Sampling.
      aug:
        au:
          Dahm, Matthew M.
          Evans, Douglas E.
          Schubauer-Berigan, Mary K.
          Birch, M. Eileen
          Deddens, James A.
        affil: Division of Surveillance, Hazard Evaluations, and Field Studies, Industrywide Studies Branch, National Institute for Occupational Safety and Health, 4676 Columbia Parkway, MS-R14, Cincinnati, OH 45226, USA
      sug:
        subj:
          Occupational Exposure
          Nanotechnology
          Air Pollution, Indoor
          Nanoparticles Adverse Effects
          Carbon Adverse Effects
          Environmental Monitoring
          Human
          Microscopy, Electron
          Data Analysis Software
          Post Hoc Analysis
          Spearman's Rank Correlation Coefficient
          Descriptive Statistics
          Time Series
          Repeated Measures
          Photometry
          Industry
          Funding Source
      ab: Research Significance: Toxicological evidence suggests the potential for a wide range of health effects from exposure to carbon nanotubes (CNTs) and carbon nanofibers (CNFs). To date, there has been much focus on the use of direct-reading instruments (DRIs) to assess multiple airborne exposure metrics for potential exposures to CNTs and CNFs due to their ease of use and ability to provide instantaneous results. Still, uncertainty exists in the usefulness and interpretation of the data. To address this gap, air-monitoring was conducted at six sites identified as CNT and CNF manufacturers or users and results were compared with filter-based metrics. Methods: Particle number, respirable mass, and active surface area concentrations were monitored with a condensation particle counter, a photometer, and a diffusion charger, respectively. The instruments were placed on a mobile cart and used as area monitors in parallel with filter-based elemental carbon (EC) and electron microscopy samples. Repeat samples were collected on consecutive days, when possible, during the same processes. All instruments in this study are portable and routinely used for industrial hygiene sampling. Results: Differences were not observed among the various sampled processes compared with concurrent indoor or outdoor background samples while examining the different DRI exposure metrics. Such data were also inconsistent with results for filter-based samples collected concurrently at the same sites [Dahm MM, Evans DE, Schubauer-Berigan MK et al. (2012) Occupational exposure assessment in CNT and nanofiber primary and secondary manufacturers. Ann Occup Hyg; 56: 542–56]. Significant variability was seen between these processes as well as the indoor and outdoor backgrounds. However, no clear pattern emerged linking the DRI results to the EC or the microscopy data (CNT and CNF structure counts). Conclusions: Overall, no consistent trends were seen among similar processes at the various sites. The DRI instruments employed were limited in their usefulness in assessing and quantifying potential exposures at the sampled sites but were helpful for hypothesis generation, control technology evaluations, and other air quality issues. The DRIs employed are nonspecific, aerosol monitors, and, therefore, subject to interferences. As such, it is necessary to collect samples for analysis by more selective, time-integrated, laboratory-based methods to confirm and quantify exposures.
      pubtype: Academic Journal
      doctype:
        research
        tables/charts
        Journal Article
      ougenre: Article
    language: English
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