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Counterintuitive Mechanisms of the Addition of Hydrogen and Simple Olefins to Heavy Group 13 Alkene Analogues.

The mechanism of the reaction of olefins and hydrogen with dimetallenes ArMMAr (Ar = aromatic group; M = Al or Ga) was studied by density functional theory calculations and experimental methods. The digallenes, for which the most experimental data are available, are extensively dissociated to gallan...

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Published in:Journal of the American Chemical Society Vol. 135; no. 5; pp. 1952 - 1961
Main Authors: Caputo, Christine A., Koivistoinen, Juha, Moilanen, Jani, Boynton, Jessica N., Tuononen, Heikki M., Power, Philip P.
Format: Article
Published: American Chemical Society 2/6/2013
Subjects:
Group 13 elements
Alkenes
Hydrogen
Density functional theory
Aromatic compounds
Ring formation (Chemistry)
Ethylene
Dimerization
Online Access:View this record in EBSCOhost