Isolation of a Mixed Valence Diiron Hydride: Evidence for a Spectator Hydride in Hydrogen Evolution Catalysis.

The mixed-valence diiron hydrido complex (μ-H)Fe(pdt)(CO)(dppv) ([H1], where pdt =1,3-propanedithiolate and dppv = cis-1,2-CH(PPh)), was generated by reduction of the differous hydride [H1] using decamethylcobaltocene. Crystallographic analysis shows that [H1] retains the stereochemistry of its prec...

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Publicado en:	Journal of the American Chemical Society Vol. 135; no. 9; pp. 3633 - 3640
Autores principales:	Wenguang Wang, Nilges, Mark J., Rauchfuss, Thomas B., Stein, Matthias
Formato:	Artículo
Publicado:	American Chemical Society 3/6/2013
Materias:	Phosphorus compounds Density functionals Spectrum analysis Hydrogen analysis Stereochemistry
Acceso en línea:	Ver este registro en EBSCOhost