A Singlet Biradicaloid Zinc Compound and Its Nonradical Counterpart.

Metal ions with radical centers in their coordination sphere are key participants in biological and catalytic processes. In the present study, we describe the synthesis of the cAAC:ZnCl adduct (1) using a cyclic alkylaminocarbene (cAAC) as donor ligand. Compound 1 was treated with 2 equiv of KC and...

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Publicado en:	Journal of the American Chemical Society Vol. 135; no. 19; pp. 7324 - 7330
Autores principales:	Pratap Singh, Amit, Samuel, Prinson P., Roesky, Herbert W., Schwarzer, Martin C., Frenking, Gernot, Sidhu, Navdeep S., Dittrich, Birger
Formato:	Artículo
Publicado:	American Chemical Society 5/15/2013
Materias:	Zinc compounds synthesis Biradicals synthesis Carbenes Density functional theory Radical ions Hydrogenation
Acceso en línea:	Ver este registro en EBSCOhost