Gas Phase Acidity Measurement of Local Acidic Groups in Multifunctional Species: Controlling the Binding Sites in Hydroxycinnamic Acids.

The applicability of the extended kinetic method (EKM) to determine the gas phase acidities (GA) of different deprotonable groups within the same molecule was tested by measuring the acidities of cinnamic, coumaric, and caffeic acids. These molecules differ not only in the number of acidic groups bu...

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Publicado en:	Journal of the American Chemical Society Vol. 135; no. 26; pp. 9681 - 9691
Autores principales:	Guerrero, Andres, Baer, Tomas, Chana, Antonio, González, Javier, Dávalos, Juan Z.
Formato:	Artículo
Publicado:	American Chemical Society 7/3/2013
Materias:	American Chemical Society Gas phase reactions Molecules Density functional theory Hydroxycinnamic acids
Acceso en línea:	Ver este registro en EBSCOhost