Theoretical Study of Reactivity of Ge(II)-hydride Compound: Comparison with Rh(I)-Hydride Complex and Prediction of Full Catalytic Cycle by Ge(II)-hydride.
The reaction of a Ge(II) hydride compound HC{CMeArN}GeH (Ar = 2,6-iPrCH) 1 with 2,2,2-trifluoroacetophenone (CFPhCO) is theoretically investigated with density functional theory and spin-component-scaled second-order Møller–Plesset methods. This reaction easily occurs with moderate activation barrie...
| Publicado en: | Journal of the American Chemical Society Vol. 135; no. 24; pp. 8955 - 8966 |
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| Autores principales: | , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
6/19/2013
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| Acceso en línea: | Ver este registro en EBSCOhost |