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Sterically Directed Functionalization of the Redox-Active Bis(imino)acenaphthene Ligand Class: An Experimental and Theoretical Investigation.

The synthesis, characterization, and theoretical study of the sterically directed functionalization of the redox-active bis(imino)acenaphthene (BIAN) ligand class has been explored. With dependence on the steric congestion encompassing the N-C-C-N fragment of the Ar-BIAN ligand, functionalization ca...

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Published in:Journal of the American Chemical Society Vol. 135; no. 37; pp. 13939 - 13947
Main Authors: Evans, Daniel A., Vargas-Baca, Ignacio, Cowley, Alan H.
Format: Article
Published: American Chemical Society 9/18/2013
Subjects:
Chemical reactions
Optical diffraction
Hydrocarbons
Molecular structure of ligands
Coordination compounds
Ligand exchange reactions
Online Access:View this record in EBSCOhost