Photoinduced Solid State Conversion of a Radical σ-Dimer to a π-Radical Pair.

Irradiation in the solid state of the hypervalent 4c-6e S···S–S···S bridged σ-dimer of a bisdithiazolyl radical leads to its photodissociation into a pair of π-radicals. The transformation has been monitored by optical spectroscopy, single crystal X-ray diffraction, and magnetic susceptibility measu...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 135; no. 42; pp. 15674 - 15678
Main Authors:	Hoa Phan, Lekin, Kristina, Winter, Stephen M., Oak1ey, Richard T., Shatruk, Michael
Format:	Article
Published:	American Chemical Society 10/23/2013
Subjects:	Dimers Geminate pairs (Molecules) Solid state chemistry Hypervalence (Theoretical chemistry) Photodissociation Single crystals X-ray diffraction Magnetic susceptibility
Online Access:	View this record in EBSCOhost