Dipalladium(I) Terphenyl Diphosphine Complexes as Models for Two-Site Adsorption and Activation of Organic Molecules.

A para-terphenyl diphosphine was employed to support a dipalladium(I) moiety. Unlike previously reported dipalladium(I) species, the present system provides a single molecular hemisphere for binding of ligands across two metal centers, enabling the characterization and comparison of the binding of a...

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Publicado en:	Journal of the American Chemical Society Vol. 135; no. 42; pp. 15830 - 15841
Autores principales:	Lin, Sibo, Herbert, David E., Velian, Alexandra, Day, Michael W., Agapie, Theodor
Formato:	Artículo
Publicado:	American Chemical Society 10/23/2013
Materias:	Terphenyl Diphosphine Adsorption (Chemistry) Moieties (Chemistry) Toluene Nuclear magnetic resonance spectroscopy Density functional theory Molecular orbitals
Acceso en línea:	Ver este registro en EBSCOhost