Tuning Omniphobicity via Morphological Control of Metal–Organic Framework Functionalized Surfaces.
Fabrication of microstructures for imparting omniphobicity to a surface generally requires the use of lithographic techniques and specialized equipment. We report instead a simple strategy for the synthesis of microstructured surfaces via metal–organic framework (MOF) self-assembly. Our method allow...
| Publicado en: | Journal of the American Chemical Society Vol. 135; no. 44; pp. 16272 - 16276 |
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| Autores principales: | , , , , , , |
| Formato: | Artículo |
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American Chemical Society
11/6/2013
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=92594140&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 92594140 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 11/6/2013 vid: 135 iid: 44 pid: 997 pub: American Chemical Society artinfo: ui: 92594140 10.1021/ja407896m ppf: 16272 ppct: 4 formats: tig: atl: Tuning Omniphobicity via Morphological Control of Metal–Organic Framework Functionalized Surfaces. aug: au: Tan, Tristan T. Y. Reithofer, Michael R. Chen, Eric Y. Menon, Ajay G. Andy Hor, T. S. Jianwei Xu Jia Min Chin affil: Institute of Materials Research and Engineering, 3 Research Link, Singapore 117602 Institute of Bioengineering and Nanotechnology, 31 Biopolis Way, Singapore 138669 su: Metal-organic frameworks Structural frames Organometallic compounds Microstructure Microphysics Wet chemistry Crystals Nanocrystals sug: subj: Metal-organic frameworks Structural frames Organometallic compounds Microstructure Microphysics Wet chemistry Crystals Nanocrystals ab: Fabrication of microstructures for imparting omniphobicity to a surface generally requires the use of lithographic techniques and specialized equipment. We report instead a simple strategy for the synthesis of microstructured surfaces via metal–organic framework (MOF) self-assembly. Our method allows us to localize epitaxial growth of MOF at the tips of needle crystals to create mushroom-shaped structures, thus conferring re-entrant textures to the MOF-functionalized surfaces. These structures synthesized via wet chemistry were found to have omniphobic properties due to the resulting re-entrant texture. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2013 holdings: @attributes: islocal: N |
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