Single-Crystal Structure of a Covalent Organic Framework.
The crystal structure of a new covalent organic framework, termed COF-320, is determined by single-crystal 3D electron diffraction using the rotation electron diffraction (RED) method for data collection. The COF crystals are prepared by an imine condensation of tetra-(4-anilyl)methane and 4,4′-biph...
| Published in: | Journal of the American Chemical Society Vol. 135; no. 44; pp. 16336 - 16340 |
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| Main Authors: | , , , , , , , |
| Format: | Article |
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American Chemical Society
11/6/2013
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| Online Access: | View this record in EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=92594156&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 92594156 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 11/6/2013 vid: 135 iid: 44 pid: 997 pub: American Chemical Society artinfo: ui: 92594156 10.1021/ja409033p ppf: 16336 ppct: 4 formats: tig: atl: Single-Crystal Structure of a Covalent Organic Framework. aug: au: Yue-Biao Zhang Jie Su Hiroyasu Furukawa Yifeng Yun Gándara, Felipe Duong, Adam Xiaodong Zou Yaghi, Omar M. affil: Department of Chemistry, University of California, and Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States Inorganic and Structural Chemistry and Berzelii Center EXSELENT on Porous Materials, Department of Materials and Environmental Chemistry, Stockholm University, Stockholm SE–106 91, Sweden su: Crystal structure Organic chemistry research Covalent bonds Covalent crystals Crystals Electron diffraction Optical diffraction Particles (Nuclear physics) sug: subj: Crystal structure Organic chemistry research Covalent bonds Covalent crystals Crystals Electron diffraction Optical diffraction Particles (Nuclear physics) ab: The crystal structure of a new covalent organic framework, termed COF-320, is determined by single-crystal 3D electron diffraction using the rotation electron diffraction (RED) method for data collection. The COF crystals are prepared by an imine condensation of tetra-(4-anilyl)methane and 4,4′-biphenyldialdehyde in 1,4-dioxane at 120 °C to produce a highly porous 9-fold interwoven diamond net. COF-320 exhibits permanent porosity with a Langmuir surface area of 2400 m/g and a methane total uptake of 15.0 wt % (176 cm/cm) at 25 °C and 80 bar. The successful determination of the structure of COF-320 directly from single-crystal samples is an important advance in the development of COF chemistry. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2013 holdings: @attributes: islocal: N |
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