Hemichelation, a Way To Stabilize Electron-Unsaturated Complexes: The Case of T-Shaped Pd and Pt Metallacycles.

A rational method of synthesis of stable neutral T-shaped 14 electron Pd and Pt complexes is proposed. It takes advantage of the ambiphilic character of the tricarbonyl(η-indenyl)chromium anion, of which the main property is to behave as a hemichelating ligand, that is a nonconventional heteroditopi...

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Publicado en:	Journal of the American Chemical Society Vol. 135; no. 47; pp. 17839 - 17853
Autores principales:	Werlé, Christophe, Bailly, Corinne, Karmazin-Brelot, Lydia, Le Goff, Xavier-Frédéric, Ricard, Louis, Djukic, Jean-Pierre
Formato:	Artículo
Publicado:	American Chemical Society 11/27/2013
Materias:	Metallacycles Electron research Density functionals Ligands (Chemistry) Nuclear particle research
Acceso en línea:	Ver este registro en EBSCOhost