From a Zwitterionic Phosphasilene to Base Stabilized Silyliumylidene-Phosphide and Bis(silylene) Complexes.

The reactivity of ylide-like phosphasilene 1 [LSi(TMS)═P(TMS), L = PhC(NtBu)] with group 10 d10 transition metals is reported. For the first time, a reaction of a phosphasilene with a transition metal that actually involves the silicon–phosphorus double bond was found. In the reaction of 1 with ethy...

Descripción completa

Detalles Bibliográficos

Publicado en:	Journal of the American Chemical Society Vol. 135; no. 47; pp. 17958 - 17969
Autores principales:	Breit, Nora C., Szilvási, Tibor, Tsuyoshi Suzuki, Gallego, Daniel, Shigeyoshi Inoue
Formato:	Artículo
Publicado:	American Chemical Society 11/27/2013
Materias:	Phosphorus Transition metals Silicon research Nickel Density functionals Palladium
Acceso en línea:	Ver este registro en EBSCOhost