Metal-Cation-Directed de Novo Assembly of a Functionalized Guest Molecule in the Nanospace of a Metal—Organic Framework.
In this work, a new strategy is developed to encapsulate a metal-functionalized guest molecule into a metal-organic framework (MOF) via metal-cation-directed de novo assembly from the component fragments of the guest molecule. This strategy, as illustrated in proof-of-principle studies on the de nov...
| Publicado en: | Journal of the American Chemical Society Vol. 136; no. 4; pp. 1202 - 1206 |
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| Autores principales: | , , , , , |
| Formato: | Artículo |
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American Chemical Society
1/29/2014
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=94488510&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 94488510 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 1/29/2014 vid: 136 iid: 4 pid: 997 pub: American Chemical Society artinfo: ui: 94488510 10.1021/ja410868r ppf: 1202 ppct: 4 formats: tig: atl: Metal-Cation-Directed de Novo Assembly of a Functionalized Guest Molecule in the Nanospace of a Metal—Organic Framework. aug: au: Baiyan Li Yiming Zhang Dingxuan Ma Tianliang Ma Zhan Shi Shengqian Ma affil: Department of Chemistry, University of South Florida, Tampa, Florida 33620, United States State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China College of Resource and Environmental Science, Jilin Agricultural University, Changchun 130118, China su: Metal-organic frameworks Structural frames Molecules Cations Biomolecules Porous materials Phthalocyanines sug: subj: Metal-organic frameworks Structural frames Molecules Cations Biomolecules Porous materials Phthalocyanines ab: In this work, a new strategy is developed to encapsulate a metal-functionalized guest molecule into a metal-organic framework (MOF) via metal-cation-directed de novo assembly from the component fragments of the guest molecule. This strategy, as illustrated in proof-of-principle studies on the de novo assembly of metal(II) phthalocyanine molecules into bio-MOF-1, can circumvent some drawbacks of existing approaches for encapsulating guest molecules into MOFs, such as inaccessibility for larger guest molecules due to limitations of the MOF window size and disruption of the MOF framework structure by functionalized guest molecules. Overall, this work provides a general yet versatile approach for encapsulating a broader range of metal-functionalized guest molecules into MOFs for various applications. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2014 holdings: @attributes: islocal: N |
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